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The article of NIIC researches S.A. Adonin, P.A. Abramov, M.N. Sokolov, V.P. Fedin is published in Chemical Communications (IF 6.718):
[HIrIVW6O24]7–, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7– can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.