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As the result of international collaboration the article of NIIC researches Denis G. Samsonenko and Kira E. Vostrikova is published in Inorganic Chemistry (IF 4.794).
A new 3D coordination polymer [MnIII(acacen)]3[ReIV(CN)7] was synthesized and characterized. This is the first 3D framework among the compounds composed of homoleptic cyanometallate and [MnIII(Schiff base)] complex. Its unusual magnetic behavior results from a interplay of Re−Mn anisotropic spin coupling and ZFS effect of MnIII ions with a noncollinear orientation of the local magnetic axes in the crystal. A theoretical model of anisotropic spin coupling between orbitally degenerate [ReIV(CN)7]3− anions and MnIII ions is developed.