This is the archive site of the NIIC SB RAS.
The information on this site is not up to date.
The current website of the NIIC SB RAS is available here:


Nikolaev Institute of Inorganic Chemistry

Siberian Branch of Russian Academy of Sciences

Hot articles in high-ranking journals

05 ноября 2014 года →  Hot articles

Synthesis and characterization of a new Keggin anion containing Be

The paper of researchers from NIIC SB RAS is published in Chemical Communications (IF 6.718):

Anyushin A.V., Smolentsev A.I., Mainichev D.A., C. Vicent , Gushchin A.L., Sokolov M.N., Fedin V.P. «Synthesis and characterization of a new Keggin anion: [BeW12O40]6−» Chem. Commun., 2014, 50, P. 9083–9085. DOI: 10.1039/C4CC02456G

The first Keggin-type Be-containing heteropolyanion [BeW12O40]6− (16−) has been obtained by hydrothermal synthesis from sodium tungstate and Be(NO3)2. It was crystallized as (Bu4N)4.8Na1.2[BeW12O40] (1a) and (Me2NH2)6[BeW12O40]·4H2O (1b) salts, which were characterized by 9Be and 183W NMR, ESI-MS, CV, and single crystal X-ray diffraction analysis.

Structure of [BeW12O40]6− anion

Structure of [BeW12O40]6− anion

All leading papers