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Nikolaev Institute of Inorganic Chemistry

Siberian Branch of Russian Academy of Sciences

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11 октября 2013 года →  Hot articles

Paper in Chemical Communication

The article of NIIC researches Gayfulin Y.M., Naumov N.G., Rizhikov M.R., Smolentsev A.I., Nadolinnyi V.A., Mironov Y.V. is published in Chemical Communications (IF = 6.378).

Gayfulin Y.M., Naumov N.G., Rizhikov M.R., Smolentsev A.I., Nadolinnyi V.A., Mironov Y.V.«Heterometallic clusters with new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations»Chem. Commun., 2013, V. 49, N. 85, P. 10019–10021.DOI: 10.1039/c3cc44643c

The direct synthesis of cluster complex with new 24-electron heterometallic core {Re3Mo3S8}−.

The direct synthesis of cluster complex with new 24-electron heterometallic core {Re3Mo3S8}.

The direct synthesis of cluster complex K6[Re3Mo3S8(CN)4(CN)2/2] with new 24-electron heterometallic core {Re3Mo3S8} was reported in the paper. Dissolution of polymeric compound in the aqueous solution of KCN results in oxidation and formation of discrete paramagnetic anionic cluster [Re3Mo3S8(CN)6]6−. The electronic structures of new cluster complexes were calculated by DFT and showed good agreement with the experimental data.

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