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The communication of Sapchenko S.A., Samsonenko D.G., Dybtsev D.N., Fedin is published in Inorganic Chemistry (IF = 4.593).
«Hierarchical Guest Exchange and Step-by-Step Activation of a Biporous Coordination Framework»Inorg. Chem., 2013, V. 52, No. 17, P. 9702–9704.DOI: 10.1021/ic400940w
Highly selective separation of the mixture of S4N4 and benzene by metal–organic framework [Zn4(ur)2(ndc)4]
A unique step-by-step activation of the biporous material via formation of the intermediate host–guest complex with a labile ligand has been presented on the example of the metal–organic framework [Zn4(ur)2(ndc)4]. The difference in the chemical environment of channels allows highly selective separation of the mixture of S4N4 and benzene.